Propyl acetate synthesis
- Product Name:Propyl acetate
- CAS Number:109-60-4
- Molecular formula:C5H10O2
- Molecular Weight:102.13
71-23-8
804 suppliers
$12.00/100g
50373-55-2
0 suppliers
inquiry
109-60-4
605 suppliers
$18.00/25mL
1517-69-7
264 suppliers
$6.00/1g
16197-93-6
3 suppliers
inquiry
16197-92-5
5 suppliers
inquiry
Yield:99.9 % ee ， 69.2 % ee
Reaction Conditions:
with Candida antarctica lipase immobilized on acrylic resine in di-isopropyl ether at 40; for 24 h;Enzymatic reaction;enantioselective reaction;Solvent;
Steps:
2.5 General Procedure for the Alcoholysis of Racemic Acetates (1a-7a) with Candida antarctica- B lipase
General procedure: To 1 mmol of the racemic acetates (1a-7a) dissolved in Scheme 1 Possible pathways for enzymatic deacetylation of acetate 2 mL of organic solvent, 2 mmol of the appropriate alcohol and 12 mg of CAL-B, are added. The suspension was stirred at 40 °C for 24 h. The reaction mixture is filtered on Celite and concentrated in vacuo. The remaining acetate and the producing alcohol were separated by chromatography on silica gel (petroleum ether/ethyl acetate: 80/20) and analyzed by chiral GC. The same procedure was followed for the reactions in the presence of 60 mg of molecular sieves 4 ?.
References:
Zadi, Amna;Merabet-Khelassi, Mounia;Aribi-Zouioueche, Louisa [Catalysis Letters,2015,vol. 145,# 4,art. no. 1470,p. 1054 - 1061]
591-87-7
195 suppliers
$10.00/10g
109-60-4
605 suppliers
$18.00/25mL
71-23-8
804 suppliers
$12.00/100g
64-19-7
1680 suppliers
$10.00/25ML
109-60-4
605 suppliers
$18.00/25mL
106-94-5
580 suppliers
$10.00/5ml
64-19-7
1680 suppliers
$10.00/25ML
109-60-4
605 suppliers
$18.00/25mL
764-47-6
144 suppliers
$21.00/25mL
109-60-4
605 suppliers
$18.00/25mL