SALICYLIDENEANILINE synthesis
- Product Name:SALICYLIDENEANILINE
- CAS Number:779-84-0
- Molecular formula:C13H11NO
- Molecular Weight:197.23
Yield: 80%
Reaction Conditions:
with Fe3O4#dotNi in toluene at 160; for 15 h;Autoclave;Inert atmosphere;
Steps:
16 Example 16
In a 20 mL autoclave-containing autoclave, 1.0 mmol of 2-hydroxybenzyl alcohol was added,0.5 mmol of azobenzene and 40 mg of Ni / Fe3O4 (loading: 8.0 wt%) were added and 2 mL was addedToluene, and the inside atmosphere was replaced with nitrogen, and the reaction was stirred at 160 ° C for 15 hours. After the completion of the reaction,The selectivity of azo was 95%, the yield of imine was 95%, and the yield was 80%.
References:
Dalian Institute of Chemical Physics, Chinese Academy of Sciences;Wang, Feng;Hou, Tingting;Zhang, Chaofeng;Wang, Yehong;Wang, Min;Zhang, Zhixin;Zhang, Xiaochen;Zhang, Zhe;Liu, Huifang CN106608776, 2017, A Location in patent:Paragraph 0073; 0074
