51094-17-8
51094-17-8 結(jié)構(gòu)式
基本信息
中介四(4-羥基苯基)卟吩
5,10,15,20-四(4-羥苯基)卟啉
5,10,15,20-四(4-羥基苯基)卟啉
5,10,15,20-四(4-羥基苯)-21H,23H-卟啉
5,10,15,20-四(4-羥苯基)-21H,23H-卟吩
5,10,15,20-四(4-羥基苯基)-21H,23H-卟吩
5,10,15,20-四(4-羥苯基)-21H,23H-卟吩 1G
5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)PORPHYRIN 5,10,15,20-四(4-羥苯基)卟啉
RARECHEM AS SA 0037
MESO-TETRA(P-HYDROXYPHENYL)PORPHINE
meso-Tetrakis(4-hydroxyphenyl)porphyrin
5,10,15,20-tetrakis(4-hydroxyphenyl)-21H
5,10,15,20-tetra(4-hydroxyphenyl)porphyrin
5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin
5,10,15,20-TETRAKIS(4-HYDROXYPHENYL)-21H,23H-PORPHINE
5,10,15,20-TETRAKIS-(4-HYDROXYPHENYL)-21,23H-PORPHYRIN
5,10,15,20-Tetrakis(4-hydroxyphenyl)-21H,23H-porphyrin
物理化學性質(zhì)
hematology
histology
安全數(shù)據(jù)
Skin Corr. 1A
STOT SE 3
制備方法
109-97-7
123-08-0
51094-17-8
將6.1g對羥基苯甲醛溶解于110mL丙酸中，加入6mL二甲基亞砜（DMSO），機械攪拌混合物并加熱至128℃。將新蒸餾的3.5mL吡咯溶于10mL丙酸中，以每秒1滴的速度緩慢滴加至上述反應混合物中。隨后將反應體系溫度升至141℃，回流反應2小時。反應完成后，進行熱過濾，用丙酸洗滌濾餅兩次，得到藍色固體5,10,15,20-四(4-羥基苯基)卟啉粗品。將10g干燥的粗產(chǎn)物置于100mL圓底燒瓶中，加入20mL無水乙醇，加熱回流15分鐘后，繼續(xù)加熱1.5小時。反應液冰浴冷卻1.5小時，過濾，用乙醇洗滌兩次，得到0.6172g 5,10,15,20-四(4-羥基苯基)卟啉，收率為7.27%。最后，通過硅膠柱層析（200目）純化，使用丙酮作為洗脫液，得到純化產(chǎn)物。
參考文獻：
[1] Patent: CN105085536, 2018, B. Location in patent: Paragraph 0060; 0117-0122
[2] Journal of the American Chemical Society, 2013, vol. 135, # 49, p. 18513 - 18519
[3] Macromolecular Bioscience, 2013, vol. 13, # 6, p. 808 - 816
[4] Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 2001, vol. 364, p. 611 - 623
[5] Tetrahedron Letters, 2007, vol. 48, # 41, p. 7287 - 7290
| 報價日期 | 產(chǎn)品編號 | 產(chǎn)品名稱 | CAS號 | 包裝 | 價格 |
| 2025/12/22 | XW025109417805 | 5,10,15,20-四(4-羥苯基)卟啉 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin | 51094-17-8 | 10g | 3547元 |
| 2025/12/22 | XW025109417803 | 5,10,15,20-四(4-羥苯基)卟啉 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin | 51094-17-8 | 1g | 488元 |
| 2025/12/22 | XW025109417802 | 5,10,15,20-四(4-羥苯基)卟啉 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin | 51094-17-8 | 250mg | 141元 |