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ChemicalBook >> CAS DataBase List >>2-Fluoro-3-nitrobenzoic acid

2-Fluoro-3-nitrobenzoic acid

CAS No.
317-46-4
Chemical Name:
2-Fluoro-3-nitrobenzoic acid
Synonyms
2-fluoro-3-nitro benzic acid;2-FLUORO-3-NITROBENZOIC ACID;Benzoic acid,2-fluoro-3-nitro-;3-Carboxy-2-fluoronitrobenzene;2-fluoro-3-nitro beneficial acid;2-Fluoro-3-nitrobenzoic acid 99%;2-Fluoro-3-nitrobenzoic acid+B244;3-Pyridinecarboxylic acid, 4-aMino-;Chemicalbook3-Carboxy-2-fluoronitrobenzene
CBNumber:
CB9412637
Molecular Formula:
C7H4FNO4
Molecular Weight:
185.11
MDL Number:
MFCD06797825
MOL File:
317-46-4.mol
MSDS File:
SDS
Last updated:2026-06-30 17:22:44
Product description Number Pack Size Price
2-Fluoro-3-nitrobenzoic Acid TRC-F621923-5G 5g $96
2-Fluoro-3-nitrobenzoic Acid TRC-F621923-500MG 500mg $59
2-Fluoro-3-nitrobenzoic Acid TRC-F621923-1G 1g $73
2-Fluoro-3-nitrobenzoic acid FF34112 0.05kg $150
2-Fluoro-3-nitrobenzoic acid FF34112 0.1kg $162.25
More product size

2-Fluoro-3-nitrobenzoic acid Properties

Melting point 138 - 140°C
Boiling point 347.6±27.0 °C(Predicted)
Density 1.568±0.06 g/cm3(Predicted)
storage temp. 2-8°C
solubility DMSO (Sparingly), Methanol (Slightly)
pka 2.32±0.20(Predicted)
form Solid
color White to Off-White
Water Solubility Slightly soluble in water.
Sensitive Air Sensitive
Stability Hygroscopic
InChI InChI=1S/C7H4FNO4/c8-6-4(7(10)11)2-1-3-5(6)9(12)13/h1-3H,(H,10,11)
InChIKey WLGUSLGYTNJJFV-UHFFFAOYSA-N
SMILES C(O)(=O)C1=CC=CC([N+]([O-])=O)=C1F

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Safety Statements  24/25
HS Code  29163990
NFPA 704
0
2 0

2-Fluoro-3-nitrobenzoic acid price More Price(69)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC TRC-F621923-5G 2-Fluoro-3-nitrobenzoic Acid 317-46-4 5g $96 2026-06-03 Buy
TRC TRC-F621923-500MG 2-Fluoro-3-nitrobenzoic Acid 317-46-4 500mg $59 2026-06-03 Buy
TRC TRC-F621923-1G 2-Fluoro-3-nitrobenzoic Acid 317-46-4 1g $73 2026-06-03 Buy
Biosynth FF34112 2-Fluoro-3-nitrobenzoic acid 317-46-4 0.05kg $150 2026-06-04 Buy
Biosynth FF34112 2-Fluoro-3-nitrobenzoic acid 317-46-4 0.1kg $162.25 2026-06-04 Buy
Product number Packaging Price Buy
TRC-F621923-5G 5g $96 Buy
TRC-F621923-500MG 500mg $59 Buy
TRC-F621923-1G 1g $73 Buy
FF34112 0.05kg $150 Buy
FF34112 0.1kg $162.25 Buy

2-Fluoro-3-nitrobenzoic acid Chemical Properties,Uses,Production

Chemical Properties

Light yellow crystalline powder

Uses

2-Fluoro-3-nitrobenzoic acid is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Synthesis

Concentrated sulfuric acid (195 ml) was added carefully and stirred to a solution of 2-fluoro-3-nitrotoluene (100 g, 645 mmol) in acetic acid (1000 ml). The mixture was warmed up to 95° C. The chromium trioxide solution (226 g, 2.25 mol) in water (200 ml) was added dropwise while stirring for over 2 h. After addition, the mixture was heated by stirring for another 3 h, allowed to cool down to room temperature, and poured into water (3 L). The mixture was extracted with ethyl acetate (3.x.1 L), the combined organic layers were dried over Na2SO4and concentrated under reduced pressure to afford a light green solid, which was washed with dichloromethane (3.x.300 ml) and dried under vacuum to afford 2-Fluoro-3-nitrobenzoic acid was obtained as a light yellow solid (75 g, 62.8percent). 1H NMR (300 MHz, DMSO) δ ppm 8.27 (m, 1H), 8.15 (m, 1H), 7.48 (m, 1H).

References

[1] Patent: US2009/298815, 2009, A1. Location in patent: Page/Page column 53
[2] Patent: WO2011/59610, 2011, A1. Location in patent: Page/Page column 87-88

437-86-5
317-46-4
Synthesis of 2-Fluoro-3-nitrobenzoic acid from 2-Fluoro-3-nitrotoluene
Global( 456)Suppliers
Supplier Tel Email Country ProdList Advantage
Fluoropharm Co., Ltd.
+86-0571-85586753 +86-13336034509 sales@fluoropharm.com China 1445 60
Jiangsu Guiren Medicine Co.,Ltd
+86-13815020719 guiren_medicine@163.com China 212 58
Qingdao Yonghefeng Economic and Trade Co., Ltd.
+86-13375559818 cfy69@163.com China 195 58
JiangXi Bobert Imp&Exp Co.,LTD
18071643627 rze2024@163.com China 226 58
Beijing CosmicKoda Chemical Technology Co.,Ltd
8615311061293 15311061293 JeanWangCosmicKoda@outlook.com China 49 58
Hebei Conchain Biotech Co.,Ltd
+86-13630830762 +86-13630830762 2415217937@qq.com China 135 58
.GZ HONESTCHEM CO.,LTD
+86-15013270415 honestchemical@foxmail.com China 300 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-173 9270 1263 1057@dideu.com China 3957 58
Hebei Yanxi Chemical Co., Ltd.
+86-17531190177 faithe@yan-xi.com China 5853 58
Rongchuang International
+86-13175533356 +86-13175533356 kevin@rongchuangintl.com China 257 58

View Lastest Price from 2-Fluoro-3-nitrobenzoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-FLUORO-3-NITROBENZOIC ACID pictures 2026-07-31 2-FLUORO-3-NITROBENZOIC ACID
317-46-4
$1.00 1KG 99.9% 500KG .GZ HONESTCHEM CO.,LTD
2-Fluoro-3-nitrobenzoic acid pictures 2026-07-30 2-Fluoro-3-nitrobenzoic acid
317-46-4
1kg 99%min 20tons HANGZHOU HAILAN CHEMICAL CO.,LTD.
2-Fluoro-3-nitrobenzoic acid pictures 2026-07-08 2-Fluoro-3-nitrobenzoic acid
317-46-4
1kg 99% 99999 Rongchuang International
Benzoic acid,2-fluoro-3-nitro- 2-FLUORO-3-NITROBENZOIC ACID 2-Fluoro-3-nitrobenzoic acid+B244 2-Fluoro-3-nitrobenzoic acid 99% 3-Carboxy-2-fluoronitrobenzene 3-Pyridinecarboxylic acid, 4-aMino- 2-fluoro-3-nitro benzic acid 2-fluoro-3-nitro beneficial acid Chemicalbook3-Carboxy-2-fluoronitrobenzene 317-46-4 Fluorine series Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
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