Oxadixyl
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Oxadixyl ??
- ???
- 104-105 °C
- ?? ?
- 421.12°C (rough estimate)
- ??
- 1.1674 (rough estimate)
- ???
- 1.5500 (estimate)
- ???
- >100 °C
- ?? ??
- 0-6°C
- ?? ?? (pKa)
- 1.16±0.20(Predicted)
- ???
- 25&C?? 3.4mg/L
- Merck
- 13,6976
- BRN
- 7098783
- Henry's Law Constant
- 2.0×106 mol/(m3Pa) at 25℃, Ebert et al. (2023)
- ?? ??
- agriculture
environmental
- InChI
- 1S/C14H18N2O4/c1-10-5-4-6-11(2)13(10)16(12(17)9-19-3)15-7-8-20-14(15)18/h4-6H,7-9H2,1-3H3
- InChIKey
- UWVQIROCRJWDKL-UHFFFAOYSA-N
- SMILES
- COCC(=O)N(N1CCOC1=O)c2c(C)cccc2C
- LogP
- 0.800
- CAS ??????
- 77732-09-3(CAS DataBase Reference)
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | Xn | ||
|---|---|---|---|
| ?? ???? ?? | 22 | ||
| WGK ?? | 3 | ||
| RTECS ?? | AB8131400 | ||
| ???? ??? | 11 - Combustible Solids | ||
| Hazard Classifications | Acute Tox. 4 Oral | ||
| ?? | LD50 in female rats (mg/kg): 1860 orally; >2000 dermally (Gisi) | ||
| ???? ?? | KE-11784 |
| ????(GHS): |
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| ?? ?: | Warning | ||||||||||||||
| ??·?? ??: |
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Oxadixyl C??? ??, ??, ??
??
Oxadixyl is a pesticide residue used for the detection of pesticides in vegetation.??
ChEBI: An oxazolidinone that is N-(2,6-dimethylphenyl)-2-methoxyacetamide in which the amide hydrogen is replaced by a 2-oxo-1,3-oxazolidin-3-yl group. A systemic fungicide used to treat seeds of a variety of food crops, as well as lawns.Synthesis
2,6-Dimethylphenylhydrazine reacts with 2-chloroethyl chloroformate under low-temperature (0-10°C) alkaline conditions to generate N-(2-chloroethoxycarbonyl)-N'-(2,6-dimethylphenyl)hydrazine. Subsequently, this intermediate undergoes acylation with methoxyacetyl chloride in solvents such as toluene to generate a further substituted hydrazine intermediate. Finally, under the action of a strong base (such as sodium hydroxide or sodium hydride) and a phase transfer catalyst, an intramolecular condensation cyclization reaction occurs to form a 2-oxo-1,3-oxazolidine ring, yielding Oxadixyl.Oxadixyl ?? ?? ? ???
???
Methoxyacetyl chloride
(2-METHYL-1H-INDOL-3-YL)-??-??????????
ESTRONE(RG)
2-?????????
2,6-???????
Oxazole
?? ??
Oxadixyl ?? ??
???( 111)?? ??
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Oxadixyl ?? ??:
N,N-????????? ??????? ?????????? 2-??? ???
4-Methoxyphenylacetone
Chlorodimethylphenylsilane
Thiodiazole copper
Fenasi
TRIMETHYLTIN CHLORIDE
Oxazole
3-AMINO-2-OXAZOLIDINONE
2,2'-hydrazodiethanol
(2,6-DIMETHYL-PHENYL)-HYDRAZINE
Oxadixyl
Oxadixyl+Mancozeb,W.P.
OXADIXYL SOLUTION 100UG/ML IN TOLUENE 1ML
OXADIXYL SOLUTION 100UG/ML IN ACETONITRILE 1ML
Methoxy