ChemicalBook >?? ???? >?? ??>?? ??>?? ???>1,2,3,4-??????????

1,2,3,4-??????????

1,2,3,4-?????????? ??? ???

?? ??:: 942-01-8

???:: 1,2,3,4-??????????

???(??):: 1,2,3,4-??????????

???:: 1,2,3,4-Tetrahydrocarbazole

???(??):: 2,3,4,9-TETRAHYDRO-1H-CARBAZOLE;Tetrahydrocarbazole;1H-Carbazole, 2,3,4,9-tetrahydro-;AKOS B029742;AURORA 15341;AKOS BBS-00002900;IFLAB-BB F1918-0039;TIMTEC-BB SBB003845;1,2,3,4-Tetrahydroca;OTAVA-BB BB7010090010

CBNumber:: CB9458712

???:: C12H13N

??? ??:: 171.24

MOL ??:: 942-01-8.mol

MSDS

?? ?? 232

1,2,3,4-?????????? ??

???: 118-120 °C (lit.)

?? ?: 325-330 °C (lit.)

??: 1.1459 (rough estimate)

???: 1.6544 (estimate)

???: 325-330°C

?? ??: Sealed in dry,Room Temperature

?? ?? (pKa): 17.84±0.20(Predicted)

??? ??: powder to crystal

??: White to Orange to Green

???: ?? ???. ???? ?? ???(?? ???).

BRN: 133771

InChI: 1S/C12H13N/c1-3-7-11-9(5-1)10-6-2-4-8-12(10)13-11/h1,3,5,7,13H,2,4,6,8H2

InChIKey: XKLNOVWDVMWTOB-UHFFFAOYSA-N

SMILES: C1CCc2c(C1)[nH]c3ccccc23

CAS ??????: 942-01-8(CAS DataBase Reference)

NIST: 1H-Carbazole, 2,3,4,9-tetrahydro-(942-01-8)

?? ? ?? ??
?? ? ???? ?? (GHS)

??? ??	Xi
?? ???? ??	36/37/38
?????	26-37/39
WGK ??	2
RTECS ??	FE6300000
HS ??	29339900
???? ???	11 - Combustible Solids
Hazard Classifications	Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	P- ??
H315	??? ??? ???	????? ?? ?????	?? 2	??	P264, P280, P302+P352, P321,P332+P313, P362
H319	?? ?? ??? ???	?? ? ?? ?? ??? ??	?? 2A	??	P264, P280, P305+P351+P338,P337+P313P
H335	?? ???? ??? ? ??	?? ???? ?? - 1? ??;???? ??	?? 3	??

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P264	?? ??? ?? ??? ????.
P264	?? ??? ?? ??? ????.
P271	?? ?? ??? ? ?? ???? ?????.
P280	????/???/???/?????? ?????.
P302+P352	??? ??? ??? ?? ????.
P305+P351+P338	?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

NFPA 704

	1
0		0

1,2,3,4-?????????? MSDS

1,2,3,4-Tetrahydrocarbazole

1,2,3,4-?????????? C??? ??, ??, ??

??? ??

beige crystalline powder

??

1,2,3,4-Tetrahydrocarbazole can be used as a starting material to prepare:

Spiro[cyclopentane-1,2′-indolin-3′-one] by photooxygenation.
9-Acyl-1,2,3,4-tetrahydrocarbazoles by N-acylation reactions.
Carbazole via palladium-catalyzed asymmetric hydrogenation reaction.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 14, p. 934, 1966 DOI: 10.1248/cpb.14.934
Tetrahedron Letters, 26, p. 161, 1985 DOI: 10.1016/S0040-4039(00)61869-5

1,2,3,4-?????????? ?? ?? ? ???

???

?? ??

????? 1,2,3,9-???????-4(H)-????-4-? 9-[(5-chloro-1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene)ethylidene]-2,3,4,4a,9,9a-hexahydro-1H-carbazolium chloride 9-??-2,3,4,9-??????-1H-???

1,2,3,4-?????????? ?? ??

???( 232)?? ??

???	??	???	??	?? ?	??
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1,2,3,4-?????????? ?? ??:

???????? ??????? ???????? ????????? ????????? ???? cis-1,2,3,6-Tetrahydrophthalic anhydride Methyl tetrahydrophthalic anhydride POLY(N-VINYLCARBAZOLE) 6-CHLORO-1 2 3 4-TETRAHYDROCARBAZOLE 9&,6-CHLORO-1,2,3,4-TETRAHYDROCARBAZOLE, 98 % carbazol-4-one hydrochloride 4-OXO-1,2,3,4-TETRAHYDROCARBAZOLE N-METHYL-4-OXO-1,2,3,4-TETRAHYDROCARBAZOLE 3-Dimethylaminomethyl-1,2,3,4-tetrahydro-9-methylcarbazol-4-one 3-Amino-1,2,3,4-tetrahydrocarbazol 4-OXO-1,2,3,4-TETRAHYDROCARBAZOLE (S)-3-Amino-1,2,3,4-tetrahydrocarbazole N-BENZYL-1,2,3,4-TETRAHYDROCARBAZOLE 3-METHYL-1,2,3,4-TETRAHYDROCARBAZOLE 1,2,3,4-TETRAHYDROCARBAZOLE-1-ONE

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