4,4'-DIFLUOROBENZIL synthesis
- Product Name:4,4'-DIFLUOROBENZIL
- CAS Number:579-39-5
- Molecular formula:C14H8F2O2
- Molecular Weight:246.21
24133-58-2
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579-39-5
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Yield:579-39-5 78%
Reaction Conditions:
with 1-butyl-3-methylimidazolium hydrogen sulfate;sodium bromate in water at 60; for 0.833333 h;Green chemistry;
Steps:
General procedure for the oxidation of 1,2-diols, a-hydroxyketones and alcohols to 1,2-diketones and aldehydes/ketones
General procedure: In a typical experiment, a mixture of 1,2-diols/a-hydroxyketones/alcohols (1 mmol), sodium bromate (3 mmol),and bmim[HSO4]:H2O 3:1 (v/v) along with a stir bar was placed in a RB flask fitted with a condenser. The reaction mixture was stirred magnetically in an oil-bath maintained at 60 C for an appropriate time as mentioned in Tables 3,4, and 5, respectively. After completion of the reaction, as monitored by TLC using petroleum ether:ethyl acetate(80:20, v/v) as eluent, the reaction mixture was cooled to room temperature and worked up as mentioned above. The product obtained was identified by m.p (wherever applicable), IR and NMR spectra.
References:
Khurana, Jitender M.;Lumb, Anshika;Chaudhary, Ankita [Monatshefte fur Chemie,2017,vol. 148,# 2,p. 381 - 386]
1493-51-2
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579-39-5
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403-43-0
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$9.00/25g
579-39-5
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459-57-4
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579-39-5
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5216-31-9
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$90.00/250mg
579-39-5
135 suppliers
$38.00/1g