METHYL 4-CHLOROBENZOATE synthesis
- Product Name:METHYL 4-CHLOROBENZOATE
- CAS Number:1126-46-1
- Molecular formula:C8H7ClO2
- Molecular Weight:170.59
Yield:1126-46-1 95%
Reaction Conditions:
with diiron nonacarbonyl at 180; for 1 h;Sealed tube;
Steps:
General procedure for the reaction of dimethyl carbonate with carboxylic acids.
General procedure: 1-3 mmol of catalyst Mn 2 (CO) 10 , 100 mmol of the carboxylic acid, and 300-400 mmol of dimethyl carbonate were placed into a 17 mL stainless steel microreactor. The reactor was sealed, and the reaction mixture was heated at 180° for 1 h. After the reaction was complete, the reactor was cooled to room temperature and opened. The reaction mixture was filtered through a layer of Al 2 O 3 . Unreacted dimethyl carbonate was distilled off, the residue was distilled at atmospheric or reduced pressure, or crystallized.
References:
Khusnutdinov;Shchadneva;Mayakova, Yu. Yu. [Russian Journal of General Chemistry,2018,vol. 88,# 1,p. 15 - 19][Zh. Obshch. Khim.,2018,vol. 88,# 1,p. 18 - 22,5]
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1126-46-1
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