N-OCTANE synthesis
- Product Name:N-OCTANE
- CAS Number:111-65-9
- Molecular formula:C8H18
- Molecular Weight:114.23
4128-31-8
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111-65-9
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Yield:111-65-9 99%
Reaction Conditions:
with hydrogen;AIOTfbpy-Pd in 1,2-dichloro-ethane at 150; under 37503.8 Torr; for 24 h;Glovebox;Inert atmosphere;
Steps:
1
General procedure: As shown in Scheme 1, above, in a nitrogen-filled glovebox, AlOTf-bpy-Pd (2.0 mg, 1.2 μmol AlOTf sites), 1,8-cineole (100 μL, 0.6 mmol), and 1.0 mL of 1,2-dichloroethane were transferred into a Parr reactor. The Parr reactor was then sealed under nitrogen, purged with hydrogen several times and charged with hydrogen to 50 bar. After stirring at 100° C. for 24 hours, the pressure was released and the MOF catalyst was removed from the reaction mixture via centrifugation. The supernatant was analyzed by GC-MS to give menthane (a mixture of cis/trans isomers) in >99% yield with 100% of substrate conversion.
References:
US2021/53042,2021,A1 Location in patent:Paragraph 0166; 0168
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111-65-9
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