Octanoic acid synthesis
- Product Name:Octanoic acid
- CAS Number:124-07-2
- Molecular formula:C8H16O2
- Molecular Weight:144.21
124-13-0
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$7.00/25g
124-07-2
774 suppliers
$6.00/25g
Yield:124-07-2 99%
Reaction Conditions:
with tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III);oxygen in acetonitrile at 20;Irradiation;Sealed tube;Green chemistry;chemoselective reaction;
Steps:
Synthesis of carboxylic acids
General procedure: An oven-dried resealable test tube equipped with a magnetic stir bar was charged withaldehyde (1.0 mmol), Ir(dFppy)3 (0.005-0.01 mmol), and MeCN (4.0 mL, 0.25 M). Oxygen wasthen bubbled through the reaction mixture and sealed with a silicone septa screw-cap. A balloonfilled with oxygen was attached to the tube, and the test tube was placed under blue LEDs atroom temperature. The reaction was allowed to proceed for 3-12 h, and reaction progress waschecked by TLC. The solvent was removed under vacuum, and the corresponding carboxylic acidwas purified by flash silica gel chromatography.
References:
Iqbal, Naeem;Choi, Sungkyu;You, Youngmin;Cho, Eun Jin [Tetrahedron Letters,2013,vol. 54,# 46,p. 6222 - 6225] Location in patent:supporting information
1974-04-5
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$84.79/25g
124-38-9
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$214.00/14L
124-07-2
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$6.00/25g
111-87-5
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$6.00/100g
124-07-2
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$6.00/25g
698-76-0
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$50.00/250mg
124-07-2
774 suppliers
$6.00/25g