Tributylphosphine synthesis
- Product Name:Tributylphosphine
- CAS Number:998-40-3
- Molecular formula:C12H27P
- Molecular Weight:202.32
3084-50-2
13 suppliers
$78.00/25g
998-40-3
342 suppliers
$18.32/25g
Yield:998-40-3 92 %Chromat.
Reaction Conditions:
with [AlH3(triethylamine)] in hexane at 20; for 0.166667 h;Inert atmosphere;Schlenk technique;
Steps:
Compound IIIa (general procedure).
General procedure: Triphenylphosphine oxide or sulfide (1 mmol), dry hexane (1 mL), and Ic (1 mmol) were added to a Schlenk tube under the atmosphere of nitrogen. The reaction was carried out at room temperature for 10 min and monitored by TLC. Upon completion of the process the reaction mixture was filtered by silica gel and washed several times with ethyl acetate. Ethyl acetate was evaporated and the residue purified by flash chromatography on silica gel with pure cyclohexane toafford the desired phosphine. The yield was determined by GC without additional purification.
References:
Yang, Shuyan;Han, Xinxin;Luo, Minmin;Gao, Jing;Chu, Wenxiang;Ding, Yuqiang [Russian Journal of General Chemistry,2015,vol. 85,# 5,p. 1156 - 1160][Zh. Obshch. Khim.]
109-69-3
447 suppliers
$20.00/100ml
998-40-3
342 suppliers
$18.32/25g
814-29-9
212 suppliers
$11.00/5g
998-40-3
342 suppliers
$18.32/25g
109-65-9
568 suppliers
$10.00/10g
998-40-3
342 suppliers
$18.32/25g
814-29-9
212 suppliers
$11.00/5g
75-16-1
268 suppliers
$12.00/10ml
23708-47-6
0 suppliers
inquiry
998-40-3
342 suppliers
$18.32/25g
33374-48-0
1 suppliers
inquiry
594-09-2
153 suppliers
$48.50/1g