Trioctylphosphine oxide synthesis
- Product Name:Trioctylphosphine oxide
- CAS Number:78-50-2
- Molecular formula:C24H51OP
- Molecular Weight:386.63
method 2: preparing the trioctylphosphine oxide from the sodium hypophosphite by performing the octene addition, the trichlorosilane reduction, the hydrolysis and the octene addition again in turn;
method 3: preparing the trioctylphosphine oxide from the sodium hypophosphite by performing the octene addition, the trichlorosilane reduction and alcoholysis in turn.
Yield:78-50-2 81.4%
Reaction Conditions:
with acetic acid at 120 - 135; for 8 h;
Steps:
2.2
2 g of dioctylphosphine oxide (0.007mol) is added into 20 ml of acetic acid, after heating at 120 ° C, slowly added the drops of 2.2 (0.020 mol) g of octane, continue heating at 135 ° C for 8 hours, 31PNMR detection reaction end point, after the reaction is completed, add chloroform and distilled water, remove acetic acid, the chloroform is distilled off under reduced pressure (400 Pa, 35 ° C), Vacuum drying (120 Pa, 25 ° C) and obtained white solid, 2.2 g (0.0057 mol). Yield is 81.4%.
References:
Tianjin Jinzu Technology Co., Ltd.;Duo Wenbin CN103232488, 2017, B Location in patent:Paragraph 0063
4731-53-7
227 suppliers
$11.19/5ML
78-50-2
252 suppliers
$18.00/5g
111-83-1
508 suppliers
$12.00/25g
3011-82-3
1 suppliers
inquiry
78-50-2
252 suppliers
$18.00/5g
6196-68-5
0 suppliers
inquiry
4731-53-7
227 suppliers
$11.19/5ML
22585-81-5
1 suppliers
inquiry
78-50-2
252 suppliers
$18.00/5g
1005-33-0
1 suppliers
inquiry