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ChemicalBook CAS DataBase List TriMethyl(broModifluoroMethyl)silane
115262-01-6

TriMethyl(broModifluoroMethyl)silane synthesis

5synthesis methods
A flask equipped with a reflux condenser was filled with NaBr (10.8 g, 105 mmol), 30% aqueous H2O2 solution (14.2 g, 125 mmol) and water (7 mL). The mixture was cooled in an ice/water bath and concentrated sulfuric acid (6.7 mL, 125 mmol) was added dropw
65864-64-4 Synthesis
(Difluoromethyl)trimethylsilane

65864-64-4
142 suppliers
$20.00/1g

-

Yield:115262-01-6 80%

Reaction Conditions:

with sulfuric acid;dihydrogen peroxide;sodium bromide in water at 40; for 1 h;Irradiation;Inert atmosphere;

References:

Kosobokov, Mikhail D.;Dilman, Alexander D.;Levin, Vitalij V.;Struchkova, Marina I. [Journal of Organic Chemistry,2012,vol. 77,# 13,p. 5850 - 5855] Location in patent:supporting information; experimental part

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