4-Chloranisol
|
|
|
- CAS-Nr.
- 623-12-1
- Bezeichnung:
- 4-Chloranisol
- Englisch Name:
- 4-Chloroanisole
- Synonyma:
- 1-CHLORO-4-METHOXYBENZENE;P-CHLOROANISOLE;para-Chloroanisole;4-Methoxyphenyl chloride;4-Chloroanisol;p-chloroanisol;Chloro anisole;4-CHLOROANISOLE;3 4-Chloroanisole;Anisole, p-chloro-
- CBNumber:
- CB1312283
- Summenformel:
- C7H7ClO
- Molgewicht:
- 142.58
- MOL-Datei:
- 623-12-1.mol
|
4-Chloranisol Eigenschaften
- Schmelzpunkt:
- ?18 °C (lit.)
- Siedepunkt:
- 198-202 °C (lit.)
- Dichte
- 1.164 g/mL at 25 °C (lit.)
- Dampfdruck
- 1.08hPa at 25℃
- Brechungsindex
- n20/D 1.535(lit.)
- Flammpunkt:
- 173 °F
- storage temp.
- Sealed in dry,Room Temperature
- Aggregatzustand
- Liquid
- Farbe
- Clear colorless to yellow
- Wasserl?slichkeit
- immiscible
- BRN
- 1858901
- Henry's Law Constant
- 5.8×10-2 mol/(m3Pa) at 25℃, Pfeifer et al. (2001)
- Stabilit?t:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- InChI
- 1S/C7H7ClO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
- InChIKey
- YRGAYAGBVIXNAQ-UHFFFAOYSA-N
- SMILES
- COc1ccc(Cl)cc1
- LogP
- 2.78 at 25℃
- CAS Datenbank
- 623-12-1(CAS DataBase Reference)
- NIST chemische Informationen
- Benzene, 1-chloro-4-methoxy-(623-12-1)
- EPA chemische Informationen
- Benzene, 1-chloro-4-methoxy- (623-12-1)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
Xn |
|
|
| S-S?tze: |
23-24/25 |
|
|
| RIDADR |
UN 2810 |
|
|
| WGK Germany |
3 |
|
|
| TSCA |
TSCA listed |
|
|
| HS Code |
29093090 |
|
|
| Speicherklasse |
10 - Combustible liquids |
|
|
| Bildanzeige (GHS) |
|
| Alarmwort |
Warnung
|
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H227 |
Combustible liquid |
Flammable liquids |
Category 4 |
Warnung |
|
P210, P280, P370+P378, P403+P235,P501 |
|
| Sicherheit |
| P210 |
Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P403+P235 |
An einem gut belüfteten Ort aufbewahren. Kühl halten. |
| P501 |
Inhalt/Beh?lter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen. |
|
4-Chloranisol Chemische Eigenschaften,Einsatz,Produktion Methoden
S-S?tze Betriebsanweisung:
S23:Gas/Rauch/Dampf/Aerosol nicht einatmen(geeignete Bezeichnung(en) vom Hersteller anzugeben).
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
colourless liquid
Verwenden
4-Chloroanisole was found to react with Cu (II)-smectite forming a blue clay-organic complex. 4-Chloroanisole was chosen as the main test substrate for the optimisation studies as it is electronically deactivated and thus resistant to oxidative addition and consequently very reluctant to enter a catalytic manifold.
Allgemeine Beschreibung
4-Chloroanisole is an electron-rich chloroarene. It undergoes Ullmann-type homocoupling catalyzed by
in situ generated Pd colloids. Reaction of 4-chloroanisole with Cu(II)-smectite in
n-hexane, carbon tetrachloride or dichloromethane has been studied. The nucleophilic photosubstitution reactions, photocyanation and photohydrolysis of 4-chloroanisole has been studied by time resolved spectroscopy.
l?uterung methode
Wash the anisole with 10% (by volume) aqueous H2SO4 (three times), 10% aqueous KOH (three times), and then with water until neutral. Dry it (MgSO4), and fractionally distil it from CaH2 through a glass helices-packed column under reduced pressure. [Beilstein 16 IV 822.]
4-Chloranisol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
4-Chloranisol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 363)Lieferanten
623-12-1(4-Chloranisol)Verwandte Suche:
- 1-chloro-4-methoxy-benzen
- 4-Chloroanisol
- 4-Chlorophenol methyl ether
- Anisole, p-chloro-
- Benzene,1-chloro-4-methoxy-
- p-chloroanisol
- p-Chloromethoxybenzene
- p-Chlorophenyl methyl ether
- 4-CHLOROANISOLE
- Chloro anisole
- 4-chloroMethyl ether
- 3 4-Chloroanisole
- 4-Chlorophenyl methyl ether
- 4-CHLOROANISOLE PESTANAL
- 4-Chloroanisole,98%
- 2-methyl-4-chloro phenol，4-chloro anisole
- Methyl(4-chlorophenyl) ether
- 4-Chloroanisole,99%
- 4-Chloroanisole >
- para-Chloroanisole
- 4-Methoxyphenyl chloride
- 2,4-Dichlorobenzyl Alcohol Impurity 62
- C11362000 4-Chloroanisole
- 1-CHLORO-4-METHOXYBENZENE
- P-CHLOROANISOLE
- 623-12-1
- 623-12-7
- 632-12-1
- Ethers
- Building Blocks
- Oxygen Compounds
- Organic Building Blocks
- Aromatic Ethers
- Anisoles, Alkyloxy Compounds & Phenylacetates
- Chlorine Compounds
- Ethers
- Organic Building Blocks
- Oxygen Compounds
- 623-12-1
- K00001
