PHENYL FORMATE synthesis
- Product Name:PHENYL FORMATE
- CAS Number:1864-94-4
- Molecular formula:C7H6O2
- Molecular Weight:122.12
64-18-6
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108-95-2
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1864-94-4
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$6.00/1g
Yield:1864-94-4 98.4%
Reaction Conditions:
with toluene-4-sulfonic acid in toluene at 105; for 4 h;Reagent/catalyst;Solvent;Temperature;
Steps:
1.1
step one,Weigh 18.8g (0.2mol) of phenolFormic acid 11.04g (0.24mol),p-Toluenesulfonic acid 3.8g (0.02mol) andToluene 200mL,Add to the reaction flask with heating jacket and condensation refluxerUnder magnetic stirring,The reaction solution in the reaction flask was heated to 105° C. for 4 hours by heating jacket, and the esterification reaction was performed.Stop heating after esterificationWhen the temperature of the reaction solution drops to 40°C,Then, the reaction solution was distilled, and a fraction at 171°C to 173°C was collected to obtain 24.0 g of colorless phenyl formate with a yield of 98.4% and a purity of 99.2% (GC purity).
References:
Northwest Chemical Institute;Liu Weitao;Zhang Lilong;Wang Xianpei;Zhang Huihui;Li Xiaoan;Yan Jun CN107935834, 2018, A Location in patent:Paragraph 0026; 0032; 0038; 0044
5312-73-2
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108-95-2
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1864-94-4
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$6.00/1g
4249-72-3
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100-52-7
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1864-94-4
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70110-65-5
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100-52-7
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1864-94-4
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65-85-0
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